Könyv Electronic and Atomic Structure for Energy Storage Materials Abhijeet R. Shelke

Electronic and Atomic Structure for Energy Storage Materials

Nyelv: Angol
Kötés: Puha kötésű
Elérhetőség: Beszállítói készleten
Küldés 8-11 napon belül
27 171 Ft
Research shows that introducing eg¹ electrons through Mn³ oxidation states enhances the electrochem...

Információk a könyvről

Nyelv
Angol
Kötés
Könyv - Puha kötésű
Kiadva
2025
oldal
184
EAN
9786209087479
ISBN
6209087477
Enbook ID
50180527
Súly
292
Méretek
150 x 220 x 12

Teljes leírás

Research shows that introducing eg¹ electrons through Mn³ oxidation states enhances the electrochemical properties of MnO2 compounds. When alkali metals (Na , Li , K ) are inserted into - and beta-MnO2 structures, they cause topotactic Mn reduction and phase competition between the two forms. This cation insertion creates charge compensation and fast ion transport channels, improving charge storage and electrochemical performance, though the mechanism is not yet fully understood. During cycling, Na and K intercalation in -MnO2 induces a beta-MnO2 phase and facilitates Mn /Mn³ redox transitions. Despite promising results, issues like cyclic stability, self-discharge, and corrosion remain. X-ray absorption spectroscopy (XAS), including XANES and EXAFS, is used to study these redox and structural changes. Overall, Na and K incorporation improves MnO2 electrode stability and performance, offering potential for advanced supercapacitor applications. This study provide indetail understanding about the materials requirements for the energy storage applications in the context of electronic and atomic structure.

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