Könyv Fluorinated and Fluorine-Free Coordination Polymers Abdal-Azim Al-Terkawi

Fluorinated and Fluorine-Free Coordination Polymers

Alkaline Earth Metals, Mechanochemical Synthesis, ab initio Structures Determination, and Characterization

Nyelv: Angol
Kötés: Puha kötésű
Elérhetőség: Beszállítói készleten
Küldés 5-8 napon belül
21 276 Ft
Increasing concern towards environmental issues motivates researchers to develop synthesis methods t...

Információk a könyvről

Nyelv
Angol
Kötés
Könyv - Puha kötésű
Kiadva
2018
oldal
132
EAN
9786202323062
Enbook ID
21033202
Súly
204
Méretek
152 x 229 x 8

Teljes leírás

Increasing concern towards environmental issues motivates researchers to develop synthesis methods that are eco-friendly such as mechanochemistry which is established as green and rapid synthesis route for preparing materials. Coordination polymers are functional materials consisting of metal nodes bridged by functionalized organic linkers. The presence of fluorine improves the water stability of resulting compounds. Alkaline earth metals are handy for aqueous preparations, which open doors for further applications. Also, the abundant and biocompatibility of AE ions promise for constructing economical and non-toxic CPs with interesting properties. These materials are synthesized under solvothermal conditions. In this work, the mechanochemical syntheses are employed as a rapid and green method for synthesizing a series of coordination polymers. The fluorinated materials obtained by milling are compared to their fluorine-free counterparts under the same conditions. The crystal structures of materials obtained by milling are determined ab initio from powder X-ray diffraction data. The resulting compounds after milling are systematically investigated by different analytical methods.

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