Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

Szerző: JI-GUANG ZHANG

Nyelv:

Kötés: Puha kötésű

Kiadó: Springer International Publishing AG

Elérhetőség: Beszállítói készleten

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This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. L...

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Szerző

JI-GUANG ZHANG

Nyelv

Angol

Kötés

Könyv - Puha kötésű

Kiadva

2018

oldal

194

EAN

9783319829715

ISBN

9783319829715

Enbook ID

19415802

Kiadó

Springer International Publishing AG

Súly

3285

Méretek

155 x 235 x 10

Teljes leírás

This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (-3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the application of Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

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Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

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