Organometallic Oxidation Catalysis

Name: Organometallic Oxidation Catalysis
Brand: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
SKU: 9783540372097
Price: 77864 HUF
Availability: InStock

Szerző: Franc Meyer, Christian Limberg

Nyelv:

Kötés: Kemény kötésű

Kiadó: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG

Elérhetőség: Beszállítói készleten

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Eighty per cent of all compounds produced in the chemical and pharmaceutical industries require at l...

Információk a könyvről

Szerző

Franc Meyer, Christian Limberg

Nyelv

Angol

Kötés

Könyv - Kemény kötésű

Kiadva

2007

oldal

253

EAN

9783540372097

ISBN

3540372091

Enbook ID

01562447

Kiadó

Springer-Verlag Berlin and Heidelberg GmbH & Co. KG

Súly

571

Méretek

155 x 235 x 21

Teljes leírás

Eighty per cent of all compounds produced in the chemical and pharmaceutical industries require at least one essential catalytic step during their synthesis. At the same time the use of hydrocarbons as a feed-stock for commodity and fine chemicals typically requires an oxidation step, which is usually mediated by a transition metal compound. Consequently oxidation catalysis is a major research field in chemistry, both in academia and in industry. In many such processes, species with metal-carbon bonds are formed as key intermediates, and these processes represent the primary focus of this volume. An important aspect covered by some of the expert contributors is the use of organic ligands - and thus organometallic complex metal fragments - to achieve efficient oxidation catalysis. It has not been self-evident that organometallic complexes can survive the conditions necessary for polar oxygen-transfer reactions, but research over the last decade concerning oxo and peroxo complexes functionalized by organic ligands has clearly shown that relatively non-polar M-C bonds can be quite stable in the presence of oxidants and protic media, and that they may even be essential for the favourable activity and life-time of a catalyst. Also considered in this context is the oxidation chemistry of basic organometallic species in the gas phase, as this may reveal fundamental characteristics inherent to oxidation catalysts.

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