Könyv Self-Assembled Monolayers on Gold Substrates - Structure and Characterization Mihaela G. Georgata

Self-Assembled Monolayers on Gold Substrates - Structure and Characterization

Nyelv: Angol
Kötés: Puha kötésű
Elérhetőség: Beszállítói készleten
Küldés 14-21 napon belül
22 883 Ft
Self-assembled monolayers (SAMs) consist of densely packed long-chain organic molecules, which are c...

Információk a könyvről

Nyelv
Angol
Kötés
Könyv - Puha kötésű
Kiadva
2008
oldal
132
EAN
9783836490702
ISBN
3836490706
Enbook ID
06945217
Súly
186
Méretek
152 x 229 x 7

Teljes leírás

Self-assembled monolayers (SAMs) consist of densely packed long-chain organic molecules, which are chemisorbed on metal substrates through a sulfur head group. §The purpose of this work, is to study the arrangement and structure of SAMs by IR, XPS, NEXAFS, STM, Ellipsometry and contact angle.§While the first group of triptycenethiols and the second group of triarylaminethiols show a formation of disordered films on the gold surface, the third group of alkanethioacetates shows the formation of highly ordered monolayers. A further adsorption to upright oriented molecules is hindered due to kinetic effects.§In the case of azo-molecules it is shown that the photoisomerization process is not reversible. These molecules are not able to form highly ordered monolayers on the gold surface due to the critical effect of azo-moiety. Self-assembled monolayers (SAMs) consist of densely packed long-chain organic molecules, which are chemisorbed on metal substrates through a sulfur head group. The purpose of this work, is to study the arrangement and structure of SAMs by IR, XPS, NEXAFS, STM, Ellipsometry and contact angle. While the first group of triptycenethiols and the second group of triarylaminethiols show a formation of disordered films on the gold surface, the third group of alkanethioacetates shows the formation of highly ordered monolayers. A further adsorption to upright oriented molecules is hindered due to kinetic effects. In the case of azo-molecules it is shown that the photoisomerization process is not reversible. These molecules are not able to form highly ordered monolayers on the gold surface due to the critical effect of azo-moiety.

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