Könyv Trimetallic Nitride Template Endohedral Fullerene Derivatives Julio R. Pinzón

Trimetallic Nitride Template Endohedral Fullerene Derivatives

Synthesis, characterization and potential application in solar energy conversion

Szerző: Julio R. Pinzón
Nyelv: Angol
Kötés: Puha kötésű
Kiadó: Scholars' Press
Elérhetőség: Beszállítói készleten
Küldés 8-11 napon belül
30 726 Ft
Among renewable energy sources, solar energy has the potential to meet the world's growing demand fo...

Információk a könyvről

Nyelv
Angol
Kötés
Könyv - Puha kötésű
Kiadva
2014
oldal
212
EAN
9783639719826
ISBN
3639719824
Enbook ID
05344721
Súly
318
Méretek
152 x 229 x 12

Teljes leírás

Among renewable energy sources, solar energy has the potential to meet the world's growing demand for energy in the future. Currently there are many research efforts to prepare materials for photovoltaics including organic molecules. Among them, fullerene derivatives have been identified as promising materials for the construction of plastic solar cells. In this work the preparation and electrochemical properties of donor acceptor systems based on trimetallic nitride endohedral metallofullerenes (TNT-EMFs) for solar energy conversion is described. It was found that TNT-EMFs have an enhanced ability to stabilize charge separated states formed upon light irradiation when compared to empty cage fullerene analogues. Optimal conditions for preparing cyclopropanated Bingel-Hirsch derivaties of the most common TNT-EMFs were found. Novel D-A systems were prepared using this strategy and their electrochemical properties revealed that they form films by electro-oxidative polymerization. These films generate electrical current upon light irradiation. This work is a guideline for anyone interested in exploring the chemistry and electrochemical properties of these novel materials.

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